Phase-change material

phase change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat/cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other. The phase transition may also be between non-classical states of matter, such as the conformity of crystals, where the material goes from conforming to one crystalline structure to conforming to another, which may be a higher or lower energy state.

sodium acetate heating pad. When the sodium acetate solution crystallises, it becomes warm.
File:Heating pad in action.ogvPlay media
A video showing a "heating pad" in action

The energy released/absorbed by phase transition from solid to liquid, or vice versa, the heat of fusion is generally much higher than the sensible heat. Ice, for example, requires 333.55 J/g to melt, but then water will rise one degree further with the addition of just 4.18 J/g. Water/ice is therefore a very useful phase change material and has been used to store winter cold to cool buildings in summer since at least the time of the Achaemenid Empire.

By melting and solidifying at the phase change temperature (PCT), a PCM is capable of storing and releasing large amounts of energy compared to sensible heat storage. Heat is absorbed or released when the material changes from solid to liquid and vice versa or when the internal structure of the material changes; PCMs are accordingly referred to as latent heat storage (LHS) materials.

There are two principal classes of phase change material: organic (carbon-containing) materials derived either from petroleum, from plants or from animals; and salt hydrates, which generally either use natural salts from the sea or from mineral deposits or are by-products of other processes. A third class is solid to solid phase change.

PCMs are used in many different commercial applications where energy storage and/or stable temperatures are required, including, among others, heating pads, cooling for telephone switching boxes, and clothing.

By far the biggest potential market is for building heating and cooling. PCMs are currently attracting a lot of attention for this application due to the progressive reduction in the cost of renewable electricity, coupled with limited hours of availability, resulting in a misfit between peak demand and availability of supply. In North America, China, Japan, Australia, Southern Europe and other developed countries with hot summers peak supply is at midday while peak demand is from around 17:00 to 20:00. This creates a lot of demand for storage media.

Solid-liquid phase change materials are usually encapsulated for installation in the end application, to contain in the liquid state. In some applications, especially when incorporation to textiles is required, phase change materials are micro-encapsulated. Micro-encapsulation allows the material to remain solid, in the form of small bubbles, when the PCM core has melted.

Characteristics and classificationEdit

Latent heat storage can be achieved through changes in the State of matter from liquid→solid, solid→liquid, solid→gas and liquid→gas. However, only solid→liquid and liquid→solid phase changes are practical for PCMs. Although liquid–gas transitions have a higher heat of transformation than solid–liquid transitions, liquid→gas phase changes are impractical for thermal storage because large volumes or high pressures are required to store the materials in their gas phase. Solid–solid phase changes are typically very slow and have a relatively low heat of transformation.

Initially, solid–liquid PCMs behave like sensible heat storage (SHS) materials; their temperature rises as they absorb heat. Unlike conventional SHS materials, however, when PCMs reach their phase change temperature (their melting point) they absorb large amounts of heat at an almost constant temperature until all the material is melted. When the ambient temperature around a liquid material falls, the PCM solidifies, releasing its stored latent heat. A large number of PCMs are available in any required temperature range from −5 up to 190 °C.[1] Within the human comfort range between 20 and 30 °C, some PCMs are very effective, storing over 200 kJ/kg of latent heat, as against a specific heat capacity of around one kJ/(kg*°C) for masonry. The storage density can therefore be 20 times greater than masonry per kg if an temperature swing of 10 °C is allowed.[2] However, since the mass of the masonry is far higher than that of PCM this specific (per mass) heat capacity is somewhat offset. A masonry wall might have a mass of 200 kg/m2, so to double the heat capacity one would require additional 10 kg/m2 of PCM.

Image of 3 layers of ENRG Blanket, an organic PCM encapsulated in a poly/foil film.
[3] Example Organic Bio-based PCM in a poly/foil encapsulation for durability in building applications, where it works to reduce HVAC energy consumption and increase occupant comfort.

Organic PCMsEdit

Hydrocarbons, primarily paraffins (CnH2n+2) and lipids but also sugar alcohols.[4][5][6]

  • Advantages
    • Freeze without much supercooling
    • Ability to melt congruently
    • Self nucleating properties
    • Compatibility with conventional material of construction
    • No segregation
    • Chemically stable
    • Safe and non-reactive
  • Disadvantages
    • Low thermal conductivity in their solid state. High heat transfer rates are required during the freezing cycle. Nano composites were found to yield an effective thermal conductivity increase up to 216%.[7][8]
    • Volumetric latent heat storage capacity can be low
    • Flammable. This can be partially alleviated by specialised containment.

InorganicEdit

Salt hydrates (MxNyH2O) [9]

  • Advantages
    • High volumetric latent heat storage capacity
    • Availability and low cost
    • Sharp melting point
    • High thermal conductivity
    • High heat of fusion
    • Non-flammable
  • Disadvantages
    • Difficult to prevent incongruous melting and phase separation upon cycling, which can cause a significant loss in latent heat enthalpy.[10]
    • Corrosive to many other materials, such as metals.[11][12][13] This can be overcome by encapsulation in small quantities in non-reactive plastic.
    • Change of volume is very high in some mixtures
    • Super cooling can be a problem in solid–liquid transition, necessitating the use of nucleating agents which may become inoperative after repeated cycling
      Infinite R Energy Sheet
      Example: eutectic salt hydrate PCM with nucleation and gelling agents for long-term thermal stability and thermoplastic foil macro-encapsulation physical durability. Applied for passive temperature stabilization to result in building HVAC energy conservation.[14]

Hygroscopic materialsEdit

Many natural building materials are hygroscopic, that is they can absorb (water condenses) and release water (water evaporates). The process is thus:

  • Condensation (gas to liquid) ΔH<0; enthalpy decreases (exothermic process) gives off heat.
  • Vaporization (liquid to gas) ΔH>0; enthalpy increases (endothermic process) absorbs heat (or cools).

Whilst this process liberates a small quantity of energy, large surfaces area allows significant (1–2 °C) heating or cooling in buildings. The corresponding materials are wool insulation and earth/clay render finishes.

Solid-solid PCMsEdit

A specialised group of PCMs that undergo a solid/solid phase transition with the associated absorption and release of large amounts of heat. These materials change their crystalline structure from one lattice configuration to another at a fixed and well-defined temperature, and the transformation can involve latent heats comparable to the most effective solid/liquid PCMs. Such materials are useful because, unlike solid/liquid PCMs, they do not require nucleation to prevent supercooling. Additionally, because it is a solid/solid phase change, there is no visible change in the appearance of the PCM, and there are no problems associated with handling liquids, e.g. containment, potential leakage, etc. Currently the temperature range of solid-solid PCM solutions spans from -50 °C (-58 °F) up to +175 °C (347 °F).[15]

Nano Enhanced Phase change Materials (NePCM)Edit

Dispersing thermally conductive nanostructures is an effective method to improve the thermal performance of phase change materials (PCMs). For this purpose, nanocarbons, nanometals, and nano metal oxides have been used to develop nano-enhanced phase change materials (NePCMs) with unique thermal properties. In 2007, Khodadadi and Hosseinizadeh firstly reported on the accelerated freezing process of water enhanced by Cu nanoparticles. They reported that the freezing time of water was shortened from 3000 s to 1400 s by dispersing 20 vol.% of nanocopper. After that research, various aspects of NePCMs were investigated by other researchers.

Triplex shell-and-tube systems filled with NePCM, adding porous copper foam to NePCM, the effect of cavity aspect ratio on NePCM are some of these field that have been investigated yet.

Selection criteriaEdit

The phase change material should possess the following thermodynamic properties:[16]

  • Melting temperature in the desired operating temperature range
  • High latent heat of fusion per unit volume
  • High specific heat, high density, and high thermal conductivity
  • Small volume changes on phase transformation and small vapor pressure at operating temperatures to reduce the containment problem
  • Congruent melting

Kinetic properties

  • High nucleation rate to avoid supercooling of the liquid phase
  • High rate of crystal growth, so that the system can meet demands of heat recovery from the storage system

Chemical properties

  • Chemical stability
  • Complete reversible freeze/melt cycle
  • No degradation after a large number of freeze/melt cycle
  • Non-corrosiveness, non-toxic, non-flammable and non-explosive materials

Economic properties

  • Low cost
  • Availability


Thermophysical propertiesEdit

Common PCMsEdit

MaterialOrganic
PCM
Melting
point, Tm
Heat of
fusion, ΔHfus
kJ/kg
Heat of
fusion, ΔHfus
MJ/m3
Specific
heat, cp
solid
kJ/kg·K
Specific
heat, cp
liquid
kJ/kg·K
Density, ρ
solid
kg/m3
Density, ρ
liquid
kg/m3
Thermal
conductivity, k
solid
W/m·K
Thermal
conductivity, k
liquid
W/m·K
VHC
solid
kJ/m3·K
VHC
liquid
kJ/m3·K
Thermal
effusivity, e
solid
J/m2·K·s1/2
Cost
USD/kg
WaterNo°C (32 °F)333.6319.82.054.1869171,0001.6[17]-2.22[18]1,8804,1861,8900.001[19]
Sodium sulfate (Na2SO4·10H2O)No32.4 °C (90.3 °F)2520.05[20]
NaCl·Na2SO4·10H2ONo18 °C (64 °F)2860.05[20]
Lauric acidYes[21][22]44.2 °C (111.6 °F)[23]211.6197.71.762.271,0078621,7721,9571.60[24][25]
TME(63%) / H2O(37%)Yes[21][22]29.8 °C (85.6 °F)218.0240.92.753.581,1201,0903,0803,902
LiNO3.3H2ONo30.15 °C (86.27 °F)287[26]
Mn(NO3)2·6H2O / MnCl2·4H2O(4%)No[27][28]15–25 °C (59–77 °F)125.9221.82.342.781,7951,7284,2004,804
Na2SiO3·5H2ONo[27][28]72.2 °C (162.0 °F)267.0364.53.834.571,4501,2800.103−0.128[29]5,5545,8508018.04[30]
AluminiumNo660 °C (1,220 °F)396.91,007.20.89692,7002,375237[31][32]2,422?23,9602.05[33]
CopperNo1,085 °C (1,985 °F)208.71,769.50.38468,9408,020401[34]3,438?37,1306.81[35]
GoldNo1,064 °C (1,947 °F)63.721,166.30.12919,30017,310318[36]2,49128,14034,298[35]
IronNo1,538 °C (2,800 °F)247.31,836.60.44957,8746,98080.4[37]3,53916,8700.324[38]
LeadNo327 °C (621 °F)23.02253.20.128611,34010,66035.3[39]1,4597,1802.115[35]
LithiumNo181 °C (358 °F)432.2226.03.581653451284.8[40]1,91312,74062.22[41]
SilverNo962 °C (1,764 °F)104.61,035.80.23510,4909,320429[42]2,46532,520493[35]
TitaniumNo1,668 °C (3,034 °F)295.61,273.50.52354,5064,11021.9[43]2,3597,1908.05[44]
ZincNo420 °C (788 °F)112.0767.50.38967,1406,570116[45]2,78217,9602.16[35]
NaNO
3
No310 °C (590 °F)174[46]
NaNO
2
No282 °C (540 °F)212[46]
NaOHNo318 °C (604 °F)158[46]
KNO
3
No337 °C (639 °F)116[46]
KOHNo360 °C (680 °F)167[46]
NaOH / Na
2
CO
3
(7.2%)
No283 °C (541 °F)340[46]
NaCl(26.8%) / NaOHNo370 °C (698 °F)370[46]
NaCl / KCL(32.4%) / LiCl(32.8%)No346 °C (655 °F)281[46]
NaCl(5.7%) / NaNO
3
(85.5%) / Na
2
SO
4
No287 °C (549 °F)176[46]
NaCl / NaNO
3
(5.0%)
No284 °C (543 °F)171[46]
NaCl(5.0%) / NaNO
3
No282 °C (540 °F)212[46]
NaCl(42.5%) / KCl(20.5%) / MgCl
2
No385–393 °C (725–739 °F)410[46]
KNO
3
(10%) / NaNO
3
No290 °C (554 °F)170[46]
KNO
3
 / KCl(4.5%)
No320 °C (608 °F)150[46]
KNO
3
 / KBr(4.7%) / KCl(7.3%)
No342 °C (648 °F)140[46]
Paraffin 14-Carbons[47]Yes5.5 °C (41.9 °F)228
Paraffin 15-Carbons[47]Yes10 °C (50 °F)205
Paraffin 16-Carbons[47]Yes16.7 °C (62.1 °F)237.1
Paraffin 17-Carbons[47]Yes21.7 °C (71.1 °F)213
Paraffin 18-Carbons[47]Yes28 °C (82 °F)244
Paraffin 19-Carbons[47]Yes32 °C (90 °F)222
Paraffin 20-Carbons[47]Yes36.7 °C (98.1 °F)246
Paraffin 21-Carbons[47]Yes40.2 °C (104.4 °F)200
Paraffin 22-Carbons[47]Yes44 °C (111 °F)249
Paraffin 23-Carbons[47]Yes47.5 °C (117.5 °F)232
Paraffin 24-Carbons[47]Yes50.6 °C (123.1 °F)255
Paraffin 25-Carbons[47]Yes49.4 °C (120.9 °F)238
Paraffin 26-Carbons[47]Yes56.3 °C (133.3 °F)256
Paraffin 27-Carbons[47]Yes58.8 °C (137.8 °F)236
Paraffin 28-Carbons[47]Yes61.6 °C (142.9 °F)253
Paraffin 29-Carbons[47]Yes63.4 °C (146.1 °F)240
Paraffin 30-Carbons[47]Yes65.4 °C (149.7 °F)251
Paraffin 31-Carbons[47]Yes68 °C (154 °F)242
Paraffin 32-Carbons[47]Yes69.5 °C (157.1 °F)170
Paraffin 33-Carbons[47]Yes73.9 °C (165.0 °F)268
Paraffin 34-Carbons[47]Yes75.9 °C (168.6 °F)269
Formic acid[47]Yes7.8 °C (46.0 °F)247
Caprilic acid[47]Yes16.3 °C (61.3 °F)149
Glycerin[47]Yes17.9 °C (64.2 °F)198.7
p-Lattic acid[47]Yes26 °C (79 °F)184
Methyl palmitate[47]Yes29 °C (84 °F)205
Camphenilone[47]Yes39 °C (102 °F)205
Docasyl bromide[47]Yes40 °C (104 °F)201
Caprylone[47]Yes40 °C (104 °F)259
Phenol[47]Yes41 °C (106 °F)120
Heptadecanone[47]Yes41 °C (106 °F)201
1-Cyclohexylooctadecane[47]Yes41 °C (106 °F)218
4-Heptadacanone[47]Yes41 °C (106 °F)197
p-Joluidine[47]Yes43.3 °C (109.9 °F)167
Cyanamide[47]Yes44 °C (111 °F)209
Methyl eicosanate[47]Yes45 °C (113 °F)230
3-Heptadecanone[47]Yes48 °C (118 °F)218
2-Heptadecanone[47]Yes48 °C (118 °F)218
Hydrocinnamic acid[47]Yes48 °C (118 °F)118
Cetyl acid[47]Yes49.3 °C (120.7 °F)141
a-Nepthylamine[47]Yes59 °C (138 °F)93
Camphene[47]Yes50 °C (122 °F)238
O-Nitroaniline[47]Yes50 °C (122 °F)93
9-Heptadecanone[47]Yes51 °C (124 °F)213
Thymol[47]Yes51.5 °C (124.7 °F)115
Methyl behenate[47]Yes52 °C (126 °F)234
Diphenyl amine[47]Yes52.9 °C (127.2 °F)107
p-Dichlorobenzene[47]Yes53.1 °C (127.6 °F)121
Oxolate[47]Yes54.3 °C (129.7 °F)178
Hypophosphoric acid[47]Yes55 °C (131 °F)213
O-Xylene dichloride[47]Yes55 °C (131 °F)121
ß-Chloroacetic acid[47]Yes56 °C (133 °F)147
Chloroacetic acid[47]Yes56 °C (133 °F)130
Nitro naphthalene[47]Yes56.7 °C (134.1 °F)103
Trimyristin[47]Yes33 °C (91 °F)201
Heptaudecanoic acid[47]Yes60.6 °C (141.1 °F)189
a-Chloroacetic acid[47]Yes61.2 °C (142.2 °F)130
Bees wax[47]Yes61.8 °C (143.2 °F)177
Glyolic acid[47]Yes63 °C (145 °F)109
Glycolic acid[47]Yes63 °C (145 °F)109
p-Bromophenol[47]Yes63.5 °C (146.3 °F)86
Azobenzene[47]Yes67.1 °C (152.8 °F)121
Acrylic acid[47]Yes68 °C (154 °F)115
Dinto toluent (2,4)[47]Yes70 °C (158 °F)111
Phenylacetic acid[47]Yes76.7 °C (170.1 °F)102
Thiosinamine[47]Yes77 °C (171 °F)140
Bromcamphor[47]Yes77 °C (171 °F)174
Durene[47]Yes79.3 °C (174.7 °F)156
Methyl bromobenzoate[47]Yes81 °C (178 °F)126
Alpha napthol[47]Yes96 °C (205 °F)163
Glautaric acid[47]Yes97.5 °C (207.5 °F)156
p-Xylene dichloride[47]Yes100 °C (212 °F)138.7
Catechol[47]Yes104.3 °C (219.7 °F)207
Quinone[47]Yes115 °C (239 °F)171
Actanilide[47]Yes118.9 °C (246.0 °F)222
Succinic anhydride[47]Yes119 °C (246 °F)204
Benzoic acid[47]Yes121.7 °C (251.1 °F)142.8
Stilbene[47]Yes124 °C (255 °F)167
Benzamide[47]Yes127.2 °C (261.0 °F)169.4
Acetic acid[47]Yes16.7 °C (62.1 °F)184
Polyethylene glycol 600[47]Yes20 °C (68 °F)146
Capric acid[47]Yes36 °C (97 °F)152
Eladic acid[47]Yes47 °C (117 °F)218
Pentadecanoic acid[47]Yes52.5 °C (126.5 °F)178
Tristearin[47]Yes56 °C (133 °F)191
Myristic acid[47]Yes58 °C (136 °F)199
Palmatic acid[47]Yes55 °C (131 °F)163
Stearic acid[47]Yes69.4 °C (156.9 °F)199
Acetamide[47]Yes81 °C (178 °F)241
Methyl fumarate[47]Yes102 °C (216 °F)242

Volumetric heat capacity (VHC) J·m−3·K−1

{\displaystyle \mathrm {VHC} =\rho c_{p}}

Thermal inertia (I) = Thermal effusivity (e) J·m−2·K−1·s−1/2

{\displaystyle I={\sqrt {k\rho c_{p}}}=e={(k\rho c_{p})}^{\frac {1}{2}}}


Commercially available PCMsEdit


MaterialSupplierTypeFormMelting
point, Tm
Heat of
fusion, ΔHfus
kJ/kg
Density, ρ
solid
kg/m3
Density, ρ
liquid
kg/m3
Thermal
conductivity, k
solid
W/m·K
Thermal
conductivity, k
liquid
W/m·K
Specific heat, cp
solid
kJ/kg·K
Specific heat, cp
liquid
kJ/kg·K
ATS -35Axiotherm GmbHInorganicBulk, Macro-encapsulated-35 °C (-31 °F)290
ATS -33Axiotherm GmbHInorganicBulk, Macro-encapsulated-33 °C (-27 °F)300
ATS -23Axiotherm GmbHInorganicBulk, Macro-encapsulated-23 °C (-9 °F)300
ATS -21Axiotherm GmbHInorganicBulk, Macro-encapsulated-21 °C (-6 °F)320
ATS -16Axiotherm GmbHInorganicBulk, Macro-encapsulated-16 °C (3 °F)380
ATS -12Axiotherm GmbHInorganicBulk, Macro-encapsulated-12 °C (10 °F)360
ATS -6Axiotherm GmbHInorganicBulk, Macro-encapsulated-6 °C (21 °F)360
ATS -3Axiotherm GmbHInorganicBulk, Macro-encapsulated-3 °C (27 °F)330
ATP 2Axiotherm GmbHOrganicBulk, Macro-encapsulated2 °C (36 °F)225
ATP 4Axiotherm GmbHOrganicBulk, Macro-encapsulated4 °C (39 °F)270
ATP 6Axiotherm GmbHOrganicBulk, Macro-encapsulated6 °C (43 °F)275
ATP 12Axiotherm GmbHOrganicBulk, Macro-encapsulated12 °C (54 °F)245
ATS 13Axiotherm GmbHInorganicBulk, Macro-encapsulated13 °C (55 °F)210
ATP 16Axiotherm GmbHOrganicBulk, Macro-encapsulated16 °C (61 °F)245
ATP 18Axiotherm GmbHOrganicBulk, Macro-encapsulated18 °C (64 °F)270
ATP 20Axiotherm GmbHOrganicBulk, Macro-encapsulated20 °C (68 °F)220
ATP 23Axiotherm GmbHOrganicBulk, Macro-encapsulated23 °C (73 °F)230
ATP 28Axiotherm GmbHOrganicBulk, Macro-encapsulated28 °C (82 °F)265
ATS 30Axiotherm GmbHInorganicBulk, Macro-encapsulated30 °C (86 °F)200
ATP 36Axiotherm GmbHOrganicBulk, Macro-encapsulated36 °C (97 °F)240
ATS 43Axiotherm GmbHInorganicBulk, Macro-encapsulated43 °C (109 °F)230
ATS 50Axiotherm GmbHInorganicBulk, Macro-encapsulated50 °C (122 °F)230
ATP 52Axiotherm GmbHOrganicBulk, Macro-encapsulated52 °C (126 °F)230
ATS 58Axiotherm GmbHInorganicBulk, Macro-encapsulated58 °C (136 °F)240
ATP 60Axiotherm GmbHOrganicBulk, Macro-encapsulated60 °C (140 °F)230
ATP 70Axiotherm GmbHOrganicBulk, Macro-encapsulated70 °C (158 °F)250
ATP 78Axiotherm GmbHOrganicBulk, Macro-encapsulated78 °C (172 °F)225
ATS 84Axiotherm GmbHInorganicBulk, Macro-encapsulated84 °C (183 °F)145
ATS 89Axiotherm GmbHInorganicBulk, Macro-encapsulated89 °C (192 °F)145
ATS 115Axiotherm GmbHInorganicBulk, Macro-encapsulated115 °C (239 °F)160
CrodaTherm -22Croda[48]Bio-based OrganicBulk-22.0 °C

-7.6 °F

157903887
CrodaTherm 5Croda[48]Bio-based OrganicBulk5.0 °C

41.0 °F

41 °F

191870924
CrodaTherm 6.5Croda[48]Bio-based OrganicBulk6.5 °C

43.7 °F

184857921
CrodaTherm 9.5Croda[48]Bio-based OrganicBulk9.5 °C

49.1 °F

186858963
CrodaTherm 15Croda[48]Bio-based OrganicBulk15.0 °C

59.0 °F

177859896
CrodaTherm 19Croda[48]Bio-based OrganicBulk19.0 °C

66.2 °F

175854
CrodaTherm 21Croda[48]Bio-based OrganicBulk21.0 °C

69.8 °F

190850891
CrodaTherm 24Croda[48]Bio-based OrganicBulk24.0 °C

75.2 °F

183842949
CrodaTherm 24WCroda[48]Bio-based OrganicBulk24.0 °C

75.2 °F

184842
CrodaTherm 29Croda[48]Bio-based OrganicBulk29.0 °C

84.2 °F

207851917
CrodaTherm 32Croda[48]Bio-based OrganicBulk32.0 °C

89.6 °F

190836916
CrodaTherm 37Croda[48]Bio-based OrganicBulk37.0 °C

98.6 °F

204841957
CrodaTherm 53Croda[48]Bio-based OrganicBulk53.0 °C

127.4 °F

226829904
CrodaTherm 60Croda[48]Bio-based OrganicBulk60.0 °C

140.0 °F

217
CrodaTherm ME29PCroda[48]Bio-based OrganicMicro-encapsulated Powder29.4 °C

84.9 °F

183
CrodaTherm ME29DCroda[48]Bio-based OrganicMicro-encapsulated Dispersion 50% w/w29.4 °C

84.9 °F

183
0100- Q-50 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−50 °C (−58 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-45 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−45 °C (−49 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-40 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−40 °C (−40 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-35 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−35 °C (−31 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-30 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−30 °C (−22 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-27 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−27 °C (−17 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-25 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−25 °C (−13 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-22 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−22 °C (−8 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-20 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−20 °C (−4 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-15 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−15 °C (5 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-10 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−10 °C (14 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0100- Q-05 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated−5 °C (23 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0200- Q1 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated1 °C (34 °F)3259109801.10.584.24.1
0200- Q2 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated2 °C (36 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0200- Q4 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated4 °C (39 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0200- Q5 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated5 °C (41 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0200- Q6 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated6 °C (43 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0200- Q8 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated8 °C (46 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0300- Q10 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated10 °C (50 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0300- Q12 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated12 °C (54 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0300- Q14 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated14 °C (57 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q15 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated15 °C (59 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q16 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated16 °C (61 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q17 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated17 °C (63 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q18 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated18 °C (64 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q19 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated19 °C (66 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q20 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated20 °C (68 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q21 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated21 °C (70 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q22 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated22 °C (72 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q23 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated23 °C (73 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q24 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated24 °C (75 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q25 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated25 °C (77 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0400- Q26 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated26 °C (79 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q27 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated27 °C (81 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q28 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated28 °C (82 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q29 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated29 °C (84 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q30 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated30 °C (86 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q32 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated32 °C (90 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q35 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated35 °C (95 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q37 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated37 °C (99 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q40 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated40 °C (104 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q42 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated42 °C (108 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q45 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated45 °C (113 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q50 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated50 °C (122 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q52 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated52 °C (126 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q54 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated54 °C (129 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q56 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated56 °C (133 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q58 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated58 °C (136 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q62 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated62 °C (144 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q65 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated65 °C (149 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q68 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated68 °C (154 °F)200-235900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q70 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated70 °C (158 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q72 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated72 °C (162 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q76 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated76 °C (169 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q79 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated79 °C (174 °F)200-230900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q82 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated82 °C (180 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q85 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated85 °C (185 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q87 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated87 °C (189 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q89 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated89 °C (192 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q91 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated91 °C (196 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q93 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated93 °C (199 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q95 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated95 °C (203 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q97 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated97 °C (207 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q99 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated99 °C (210 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
0500- Q100 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated100 °C (212 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q105 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated105 °C (221 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q110 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated110 °C (230 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q114 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated114 °C (237 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q120 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated120 °C (248 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q125 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated125 °C (257 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q129 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated129 °C (264 °F)200-240900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q134 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated134 °C (273 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q140 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated140 °C (284 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q144 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated144 °C (291 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q148 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated148 °C (298 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q152 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated152 °C (306 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q155 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated155 °C (311 °F)220-250900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q159 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated159 °C (318 °F)220-280900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q161 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated161 °C (322 °F)220-280900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q169 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated169 °C (336 °F)220-280900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
1000- Q175 BioPCMPhase Change
Energy Solutions[49]
Functionalized BioPCMBulk, Macro-encapsulated175 °C (347 °F)220-280900-1250850-13000.25-2.50.2-0.72.5-4.52.3-4.1
18 C0 Infinite RInsolcorp[50]InorganicMacro-encapsulated18 °C (64 °F)20015400.541.093.14

 

21 C0 Infinite RInsolcorp[50]InorganicMacro-encapsulated21 °C (70 °F)20015400.541.093.14
23 C0 Infinite RInsolcorp[50]InorganicMacro-encapsulated23 °C (73 °F)20015400.541.093.14
25 C0 Infinite RInsolcorp[50]InorganicMacro-encapsulated25 °C (77 °F)20015400.541.093.14
29 C0 Infinite RInsolcorp[50]InorganicMacro-encapsulated29 °C (84 °F)20015400.541.093.14
savE HS 33N[51]Pluss[52]InorganicBulk−30 °C (−22 °F)2241425
savE HS 26N[53]PlussInorganicBulk−24 °C (−11 °F)22212003.6
savE HS 23N[54]PlussInorganicBulk−20 °C (−4 °F)21011400.74.93.4
savE HS 18N[55]PlussInorganicBulk−18 °C (0 °F)24210950.44
savE HS 15N[56]PlussInorganicBulk−15 °C (5 °F)28010700.535.263.4
savE HS 10N[57]PlussInorganicBulk−10 °C (14 °F)23011250.604.250.96
savE HS 7N[58]PlussInorganicBulk−6 °C (21 °F)23011200.551.763.2
savE HS 01[59]PlussInorganicBulk1 °C (34 °F)29010100.552.23.9
savE OM 03[60]PlussOrganicBulk3.5 °C (38.3 °F)2408350.1460.223
savE FS 03[61]PlussOrganicBulk3.6 °C (38.5 °F)2140.16
savE OM 05[62]PlussOrganicBulk5.5 °C (41.9 °F)1308450.1350.32.37
savE FS 05[63]PlussOrganicBulk5.9 °C (42.6 °F)1100.134
savE OM 08[64]PlussOrganicBulk9 °C (48 °F)22010500.1680.2353.1
savE OM 11[65]PlussOrganicBulk9.5 °C (49.1 °F)24010600.1180.235
savE OM 21[66]PlussOrganicBulk21 °C (70 °F)2509240.140.212.6
savE FS 21[67]PlussOrganicBulk21 °C (70 °F)1300.3
savE HS 21[68]PlussInorganicBulk22 °C (72 °F)18514000.590.823.4
savE HS 22[69]PlussInorganicBulk23 °C (73 °F)18515400.561.133.04
savE HS 24[70]PlussInorganicBulk25 °C (77 °F)18515100.551.052.3
savE HS 29[71]PlussInorganicBulk29 °C (84 °F)19015300.3820.4782.3
savE OM 29[72]PlussOrganicBulk29 °C (84 °F)2298700.1720.2933.9
savE FS 29[73]PlussOrganicBulk29 °C (84 °F)1890.45
savE OM 30[74]PlussOrganicBulk31 °C (88 °F)2008780.1230.1852.6
savE FS 30[75]PlussOrganicBulk31 °C (88 °F)1700.496
savE OM 32[76]PlussOrganicBulk32 °C (90 °F)2008700.1450.219
savE HS 34[77]PlussInorganicBulk35 °C (95 °F)15018500.470.52.4
savE OM 35[78]PlussOrganicBulk37 °C (99 °F)1978700.160.2
savE OM 37[79]PlussOrganicBulk37 °C (99 °F)2108600.130.16
savE OM 46[80]PlussOrganicBulk46 °C (115 °F)2508800.10.2
savE OM 48[81]PlussOrganicBulk48 °C (118 °F)2758750.120.2
savE OM 50[82]PlussOrganicBulk50.3 °C (122.5 °F)2508500.140.213.05
savE OM 55[83]PlussOrganicBulk55 °C (131 °F)2108400.10.163.05
savE OM 65[84]PlussOrganicBulk67 °C (153 °F)1839240.330.192.38
savE FSM 65[85]PlussOrganicBulk67 °C (153 °F)1508450.25
savE HS 89[86]PlussInorganicBulk87 °C (189 °F)1801630
PureTemp -37 [87]PureTemp LLCOrganicBulk−37 °C (−35 °F)1478801.39
PureTemp -23PureTemp LLCOrganicBulk−23 °C (−9 °F)1458602.11
PureTemp -21 [88]PureTemp LLCOrganicBulk−21 °C (−6 °F)24010601.83
PureTemp -17PureTemp LLCOrganicBulk−17 °C (1 °F)1458601.74
PureTemp -15 [89]PureTemp LLCOrganicBulk−15 °C (5 °F)28610301.84
PureTemp -12PureTemp LLCOrganicBulk−12 °C (10 °F)1688701.86
PureTemp -2 [90]PureTemp LLCOrganicBulk−5 °C (23 °F)1508601.66
PureTemp 1PureTemp LLCOrganicBulk1 °C (34 °F)30010002.32
PureTemp 4 [91]PureTemp LLCOrganicBulk4 °C (39 °F)1878802.26
PureTemp 6PureTemp LLCOrganicBulk6 °C (43 °F)1708601.56
PureTemp 8 [92]PureTemp LLCOrganicBulk8 °C (46 °F)1808601.85
PureTemp 12PureTemp LLCOrganicBulk12 °C (54 °F)1858601.76
PureTemp 15 [93]PureTemp LLCOrganicBulk15 °C (59 °F)1658602.25
PureTemp 18 [94]PureTemp LLCOrganicBulk18 °C (64 °F)1898601.47
PureTemp 20 [95]PureTemp LLCOrganicBulk20 °C (68 °F)1808602.59
PureTemp 23 [96]PureTemp LLCOrganicBulk23 °C (73 °F)2038301.84
PureTemp 24PureTemp LLCOrganicBulk24 °C (75 °F)1858602.85
PureTemp 25 [97]PureTemp LLCOrganicBulk25 °C (77 °F)1858601.99
PureTemp 27 [98]PureTemp LLCOrganicBulk27 °C (81 °F)2008602.46
PureTemp 28 [99]PureTemp LLCOrganicBulk28 °C (82 °F)2058602.34
PureTemp 29 [100]PureTemp LLCOrganicBulk29 °C (84 °F)1898501.77
PureTemp 33PureTemp LLCOrganicBulk33 °C (91 °F)1858502.34
PureTemp 35PureTemp LLCOrganicBulk35 °C (95 °F)1808502.44
PureTemp 37 [101]PureTemp LLCOrganicBulk38 °C (100 °F)2228402.21
PureTemp 48 [102]PureTemp LLCOrganicBulk48 °C (118 °F)2458202.1
PureTemp 53 [103]PureTemp LLCOrganicBulk53 °C (127 °F)2259902.36
PureTemp 58 [104]PureTemp LLCOrganicBulk58 °C (136 °F)2378102.47
PureTemp 60 [105]PureTemp LLCOrganicBulk61 °C (142 °F)2308702.04
PureTemp 63 [106]PureTemp LLCOrganicBulk63 °C (145 °F)1998401.99
PureTemp 68 [107]PureTemp LLCOrganicBulk68 °C (154 °F)1988701.85
PureTemp 108PureTemp LLCOrganicBulk108 °C (226 °F)180800
PureTemp 151 [108]PureTemp LLCOrganicBulk151 °C (304 °F)17013602.06
Astorstat HA 17Honeywell[109]OrganicBulk21.7 °C (71.1 °F)
Astorstat HA 18HoneywellOrganicBulk27.2 °C (81.0 °F)
RT26Rubitherm GmbH[110]OrganicBulk24 °C (75 °F)232
RT27Rubitherm GmbHOrganicBulk28 °C (82 °F)206
Climsel C -21Climator[111]InorganicBulk−21 °C (−6 °F)28813000.63.6
Climsel C -18ClimatorInorganicBulk−18 °C (0 °F)28813000.63.6
Climsel C 7ClimatorInorganicBulk7 °C (45 °F)12614000.63.6
Climsel C 10ClimatorInorganicBulk10.5 °C (50.9 °F)12614000.63.6
Climsel C 21ClimatorInorganicBulk21 °C (70 °F)11213800.63.6
Climsel C24ClimatorInorganicBulk24 °C (75 °F)151.313800.63.6
Climsel C28ClimatorInorganicBulk28 °C (82 °F)162.314200.63.6
Climsel C32ClimatorInorganicBulk32 °C (90 °F)162.314200.63.6
Climsel C48ClimatorInorganicBulk48 °C (118 °F)18013600.63.6
Climsel C58ClimatorInorganicBulk58 °C (136 °F)288.514600.61.89
Climsel C70ClimatorInorganicBulk70 °C (158 °F)282.914000.63.6
STL27Mitsubishi Chemicals[112]InorganicBulk27 °C (81 °F)213
S27Cristopia[113]InorganicBulk27 °C (81 °F)207
TH 29TEAP[114]InorganicBulk29 °C (84 °F)188
RT 20Rubitherm GmbHOrganicBulk22 °C (72 °F)172
Climsel C23ClimatorInorganicBulk23 °C (73 °F)14832
RT 26Rubitherm GmbHOrganicBulk25 °C (77 °F)131
RT 30Rubitherm GmbHOrganicBulk28 °C (82 °F)206
RT 32Rubitherm GmbHOrganicBulk21 °C (70 °F)130
DS 5000Micronal[115]Micro-encapsulated26 °C (79 °F)45
DS 5007MicronalMicro-encapsulated23 °C (73 °F)41
DS 5030MicronalMicro-encapsulated21 °C (70 °F)37
DS 5001MicronalMicro-encapsulated26 °C (79 °F)110
DS 5008MicronalMicro-encapsulated23 °C (73 °F)100
DS 5029MicronalMicro-encapsulated21 °C (70 °F)90
RT -9 HCRubitherm GmbHOrganicBulk−9 °C (16 °F)260
RT -4Rubitherm GmbHOrganicBulk−4 °C (25 °F)179
RT 0Rubitherm GmbHOrganicBulk0 °C (32 °F)225
RT 2 HCRubitherm GmbHOrganicBulk2 °C (36 °F)205
RT 3Rubitherm GmbHOrganicBulk3 °C (37 °F)198
RT 3 HCRubitherm GmbHOrganicBulk3 °C (37 °F)250
RT 4Rubitherm GmbHOrganicBulk4 °C (39 °F)182
RT 5Rubitherm GmbHOrganicBulk5 °C (41 °F)180
RT 5 HCRubitherm GmbHOrganicBulk5 °C (41 °F)240
RT 6Rubitherm GmbHOrganicBulk6 °C (43 °F)175
RT 8Rubitherm GmbHOrganicBulk8 °C (46 °F)180
RT 9Rubitherm GmbHOrganicBulk9 °C (48 °F)160
RT 10Rubitherm GmbHOrganicBulk10 °C (50 °F)150
RT 10 HCRubitherm GmbHOrganicBulk10 °C (50 °F)195
RT 11 HCRubitherm GmbHOrganicBulk11 °C (52 °F)190
RT 12Rubitherm GmbHOrganicBulk12 °C (54 °F)150
RT 15Rubitherm GmbHOrganicBulk15 °C (59 °F)140
RT 18 HCRubitherm GmbHOrganicBulk18 °C (64 °F)250
RT 21Rubitherm GmbHOrganicBulk21 °C (70 °F)160
RT 21 HCRubitherm GmbHOrganicBulk21 °C (70 °F)190
RT 22 HCRubitherm GmbHOrganicBulk22 °C (72 °F)200
RT 24Rubitherm GmbHOrganicBulk24 °C (75 °F)150
RT 25Rubitherm GmbHOrganicBulk25 °C (77 °F)148
RT 25 HCRubitherm GmbHOrganicBulk25 °C (77 °F)230
RT 27Rubitherm GmbHOrganicBulk27 °C (81 °F)179
RT 28 HCRubitherm GmbHOrganicBulk28 °C (82 °F)245
RT 31Rubitherm GmbHOrganicBulk31 °C (88 °F)170
RT 35Rubitherm GmbHOrganicBulk35 °C (95 °F)170
RT 35 HCRubitherm GmbHOrganicBulk35 °C (95 °F)240
RT 42Rubitherm GmbHOrganicBulk42 °C (108 °F)174
RT 44 HCRubitherm GmbHOrganicBulk44 °C (111 °F)255
RT 47Rubitherm GmbHOrganicBulk47 °C (117 °F)170
RT 50Rubitherm GmbHOrganicBulk50 °C (122 °F)168
RT 52Rubitherm GmbHOrganicBulk52 °C (126 °F)173
RT 55Rubitherm GmbHOrganicBulk55 °C (131 °F)172
RT 58Rubitherm GmbHOrganicBulk58 °C (136 °F)160
RT 60Rubitherm GmbHOrganicBulk60 °C (140 °F)144
RT 62Rubitherm GmbHOrganicBulk62 °C (144 °F)146
RT 65Rubitherm GmbHOrganicBulk65 °C (149 °F)152
RT 70 HCRubitherm GmbHOrganicBulk70 °C (158 °F)230
RT 80 HCRubitherm GmbHOrganicBulk79 °C (174 °F)240
RT 82Rubitherm GmbHOrganicBulk82 °C (180 °F)176
RT 90 HCRubitherm GmbHOrganicBulk90 °C (194 °F)200
S117PlusICE[116]InorganicBulk117 °C (243 °F)16014500.72.61
S89PlusICEInorganicBulk89 °C (192 °F)15115500.672.48
S83PlusICEInorganicBulk83 °C (181 °F)14116000.622.31
S72PlusICEInorganicBulk72 °C (162 °F)12716660.582.13
S70PlusICEInorganicBulk70 °C (158 °F)11016800.572.1
S58PlusICEInorganicBulk58 °C (136 °F)14515050.692.55
S50PlusICEInorganicBulk50 °C (122 °F)10016010.431.59
S46PlusICEInorganicBulk46 °C (115 °F)21015870.452.41
S44PlusICEInorganicBulk44 °C (111 °F)10015840.431.61
S34PlusICEInorganicBulk34 °C (93 °F)11521000.522.1
S32PlusICEInorganicBulk32 °C (90 °F)20014600.511.91
S30PlusICEInorganicBulk30 °C (86 °F)19013040.481.9
S27PlusICEInorganicBulk27 °C (81 °F)18315300.542.2
S25PlusICEInorganicBulk25 °C (77 °F)18015300.542.2
S23PlusICEInorganicBulk23 °C (73 °F)17515300.542.2
S21PlusICEInorganicBulk22 °C (72 °F)17015300.542.2
S19PlusICEInorganicBulk19 °C (66 °F)16015200.431.9
S17PlusICEInorganicBulk17 °C (63 °F)16015250.431.9
S15PlusICEInorganicBulk15 °C (59 °F)16015100.431.9
S13PlusICEInorganicBulk13 °C (55 °F)16015150.431.9
S10PlusICEInorganicBulk10 °C (50 °F)15514700.431.9
S8PlusICEInorganicBulk8 °C (46 °F)15014750.441.9
S7PlusICEInorganicBulk7 °C (45 °F)15017000.41.85
A164PlusICEOrganicBulk164 °C (327 °F)29015002.42
A155PlusICEOrganicBulk155 °C (311 °F)1009000.232.2
A144PlusICEOrganicBulk144 °C (291 °F)1158800.232.2
A133PlusICEOrganicBulk133 °C (271 °F)1268800.232.2
A118PlusICEOrganicBulk118 °C (244 °F)34014502.7
A95PlusICEOrganicBulk95 °C (203 °F)2059000.222.2
A82PlusICEOrganicBulk82 °C (180 °F)1558500.222.21
A70PlusICEOrganicBulk70 °C (158 °F)1738900.232.2
A62PlusICEOrganicBulk62 °C (144 °F)1459100.222.2
A60HPlusICEOrganicBulk60 °C (140 °F)2128000.182.15
A60HPlusICEOrganicBulk60 °C (140 °F)1459100.222.22
A58HPlusICEOrganicBulk58 °C (136 °F)2438200.182.85
A58PlusICEOrganicBulk58 °C (136 °F)1329100.222.22
A55PlusICEOrganicBulk55 °C (131 °F)1359050.222.22
A53HPlusICEOrganicBulk53 °C (127 °F)1668100.182.02
A53HPlusICEOrganicBulk53 °C (127 °F)1309100.222.22
A52PlusICEOrganicBulk52 °C (126 °F)2228100.182.15
A50PlusICEOrganicBulk50 °C (122 °F)2188100.182.15
A48PlusICEOrganicBulk48 °C (118 °F)2348100.182.85
A46PlusICEOrganicBulk46 °C (115 °F)1559100.222.22
A44PlusICEOrganicBulk44 °C (111 °F)2428050.182.15
A43PlusICEOrganicBulk43 °C (109 °F)1657800.182.37
A42PlusICEOrganicBulk42 °C (108 °F)1059050.212.22
A40PlusICEOrganicBulk40 °C (104 °F)2308100.182.43
A39PlusICEOrganicBulk39 °C (102 °F)1059000.222.22
A37PlusICEOrganicBulk37 °C (99 °F)2358100.182.85
A36PlusICEOrganicBulk36 °C (97 °F)2177900.182.37
A32PlusICEOrganicBulk32 °C (90 °F)1308450.212.2
A29PlusICEOrganicBulk29 °C (84 °F)2258100.182.15
A28PlusICEOrganicBulk28 °C (82 °F)1557890.212.22
A26PlusICEOrganicBulk26 °C (79 °F)1507900.212.22
A25HPlusICEOrganicBulk25 °C (77 °F)2268100.182.15
A25PlusICEOrganicBulk25 °C (77 °F)1507850.182.26
A24PlusICEOrganicBulk24 °C (75 °F)1457900.182.22
A23PlusICEOrganicBulk23 °C (73 °F)1457850.182.22
A22HPlusICEOrganicBulk22 °C (72 °F)2168200.182.85
A22PlusICEOrganicBulk22 °C (72 °F)1457850.182.22
A17PlusICEOrganicBulk17 °C (63 °F)1507850.182.22
A16PlusICEOrganicBulk16 °C (61 °F)2137600.182.37
A15PlusICEOrganicBulk15 °C (59 °F)1307900.182.26
A9PlusICEOrganicBulk9 °C (48 °F)1407750.212.16
A8PlusICEOrganicBulk8 °C (46 °F)1507730.212.16
A6PlusICEOrganicBulk6 °C (43 °F)1507700.212.17
A4PlusICEOrganicBulk4 °C (39 °F)2007660.212.18
A3PlusICEOrganicBulk3 °C (37 °F)2007650.212.2
A2PlusICEOrganicBulk2 °C (36 °F)2007650.212.2
E0PlusICEEutecticBulk0 °C (32 °F)33210000.584.19
E-2PlusICEEutecticBulk−2 °C (28 °F)30610700.583.8
E-3PlusICEEutecticBulk−3.7 °C (25.3 °F)31210600.63.84
E-6PlusICEEutecticBulk−6 °C (21 °F)27511100.563.83
E-10PlusICEEutecticBulk−10 °C (14 °F)28611400.563.33
E-11PlusICEEutecticBulk−11.6 °C (11.1 °F)30110900.573.55
E-12PlusICEEutecticBulk−12.3 °C (9.9 °F)25011100.563.47
E-14PlusICEEutecticBulk−14.8 °C (5.4 °F)24312200.533.51
E-15PlusICEEutecticBulk−15 °C (5 °F)30310600.533.87
E-19PlusICEEutecticBulk−18.7 °C (−1.7 °F)28211250.583.29
E-21PlusICEEutecticBulk−20.6 °C (−5.1 °F)26312400.513.13
E-22PlusICEEutecticBulk−22 °C (−8 °F)23411800.573.34
E-26PlusICEEutecticBulk−26 °C (−15 °F)26012500.583.67
E-29PlusICEEutecticBulk−29 °C (−20 °F)22214200.643.69
E-32PlusICEEutecticBulk−32 °C (−26 °F)24312900.562.95
E-34PlusICEEutecticBulk−33.6 °C (−28.5 °F)24012050.543.05
E-37PlusICEEutecticBulk−36.5 °C (−33.7 °F)21315000.543.15
E-50PlusICEEutecticBulk−49.8 °C (−57.6 °F)21813250.563.28
E-75PlusICEEutecticBulk−75 °C (−103 °F)1029020.172.43
E-78PlusICEEutecticBulk−78 °C (−108 °F)1158800.141.96
E-90PlusICEEutecticBulk−90 °C (−130 °F)907860.142.56
E-114PlusICEEutecticBulk−114 °C (−173 °F)1077820.172.39
PCM-HS26NSAVENRG[117]InorganicBulk−26 °C (−15 °F)2051200
PCM-HS23NSAVENRGInorganicBulk−23 °C (−9 °F)2001180
PCM-HS10NSAVENRGInorganicBulk−10 °C (14 °F)2201100
PCM-HS07NSAVENRGInorganicBulk−7 °C (19 °F)2301120
PCM-HS01PSAVENRGInorganicBulk0 °C (32 °F)2901010
PCM-OM05PSAVENRGOrganicBulk5 °C (41 °F)198770
PCM-0M06PSAVENRGOrganicBulk5.5 °C (41.9 °F)260735
PCM-0M08PSAVENRGOrganicBulk8 °C (46 °F)1901050
PCM-0M11PSAVENRGOrganicBulk11 °C (52 °F)2601060
PCM-0M21PSAVENRGOrganicBulk21 °C (70 °F)1201050
PCM-H22PSAVENRGInorganicBulk22 °C (72 °F)1851540
PCM-HS24PSAVENRGInorganicBulk24 °C (75 °F)1851540
PCM-HS29PSAVENRGInorganicBulk29 °C (84 °F)1901550
PCM-OM32PSAVENRGOrganicBulk32 °C (90 °F)235870
PCM-OM35PSAVENRGOrganicBulk35 °C (95 °F)197870
PCM-HS34PSAVENRGInorganicBulk34 °C (93 °F)1501850
PCM-OM37PSAVENRGOrganicBulk37 °C (99 °F)218880
PCM-OM46PSAVENRGOrganicBulk46 °C (115 °F)245860
PCM-OM48PSAVENRGOrganicBulk48 °C (118 °F)255980
PCM-OM53PSAVENRGOrganicBulk53 °C (127 °F)192860
PCM-OM65PSAVENRGOrganicBulk65 °C (149 °F)210840
PCM-HS89PSAVENRGInorganicBulk89 °C (192 °F)1801540
MPCM -30Microtek[118]OrganicMicro-encapsulated−30 °C (−22 °F)145
MPCM -30DMicrotekOrganicMicro-encapsulated−30 °C (−22 °F)145
MPCM -10MicrotekOrganicMicro-encapsulated−9.5 °C (14.9 °F)155
MPCM -10DMicrotekOrganicMicro-encapsulated−9.5 °C (14.9 °F)155
MPCM 6MicrotekOrganicMicro-encapsulated6 °C (43 °F)162
MPCM 6DMicrotekOrganicMicro-encapsulated6 °C (43 °F)162
MPCM 18MicrotekOrganicMicro-encapsulated18 °C (64 °F)168
MPCM 18DMicrotekOrganicMicro-encapsulated18 °C (64 °F)168
MPCM 28MicrotekOrganicMicro-encapsulated28 °C (82 °F)187.5
MPCM 28DMicrotekOrganicMicro-encapsulated28 °C (82 °F)187.5
MPCM28D-IRMicrotekOrganicMicro-encapsulated56 °C (133 °F)170
MPCM 37MicrotekOrganicMicro-encapsulated37 °C (99 °F)195
MPCM 37DMicrotekOrganicMicro-encapsulated37 °C (99 °F)195
MPCM 43DMicrotekOrganicMicro-encapsulated43 °C (109 °F)195
MPCM 56DMicrotekOrganicMicro-encapsulated56 °C (133 °F)170
Latest 29 TTEAPInorganicBulk28 °C (82 °F)175149012
Latest 25 TTEAPInorganicBulk24 °C (75 °F)175149012
Latest 20 TTEAPInorganicBulk19 °C (66 °F)175149012
Latest 18 TTEAPInorganicBulk17 °C (63 °F)175149012

The above dataset is also available as an Excel spreadsheet from UCLA Engineering


Technology, development and encapsulationEdit

The most commonly used PCMs are salt hydratesfatty acids and esters, and various paraffins (such as octadecane). Recently also ionic liquids were investigated as novel PCMs.

As most of the organic solutions are water-free, they can be exposed to air, but all salt based PCM solutions must be encapsulated to prevent water evaporation or uptake. Both types offer certain advantages and disadvantages and if they are correctly applied some of the disadvantages becomes an advantage for certain applications.

They have been used since the late 19th century as a medium for thermal storage applications. They have been used in such diverse applications as refrigerated transportation[119] for rail[120] and road applications[121] and their physical properties are, therefore, well known.

Unlike the ice storage system, however, the PCM systems can be used with any conventional water chiller both for a new or alternatively retrofit application. The positive temperature phase change allows centrifugal and absorption chillers as well as the conventional reciprocating and screw chiller systems or even lower ambient conditions utilizing a cooling tower or dry cooler for charging the TES system.

The temperature range offered by the PCM technology provides a new horizon for the building services and refrigeration engineers regarding medium and high temperature energy storage applications. The scope of this thermal energy application is wide-ranging of solar heating, hot water, heating rejection (i.e., cooling tower), and dry cooler circuitry thermal energy storage applications.

Since PCMs transform between solid–liquid in thermal cycling, encapsulation[122] naturally became the obvious storage choice.

  • Encapsulation of PCMs
    • Macro-encapsulation: Early development of macro-encapsulation with large volume containment failed due to the poor thermal conductivity of most PCMs. PCMs tend to solidify at the edges of the containers preventing effective heat transfer.
    • Micro-encapsulation: Micro-encapsulation on the other hand showed no such problem. It allows the PCMs to be incorporated into construction materials, such as concrete, easily and economically. Micro-encapsulated PCMs also provide a portable heat storage system. By coating a microscopic sized PCM with a protective coating, the particles can be suspended within a continuous phase such as water. This system can be considered a phase change slurry (PCS).
    • Molecular-encapsulation is another technology, developed by Dupont de Nemours that allows a very high concentration of PCM within a polymer compound. It allows storage capacity up to 515 kJ/m2 for a 5 mm board (103 MJ/m3). Molecular-encapsulation allows drilling and cutting through the material without any PCM leakage.

As phase change materials perform best in small containers, therefore they are usually divided in cells. The cells are shallow to reduce static head – based on the principle of shallow container geometry. The packaging material should conduct heat well; and it should be durable enough to withstand frequent changes in the storage material's volume as phase changes occur. It should also restrict the passage of water through the walls, so the materials will not dry out (or water-out, if the material is hygroscopic). Packaging must also resist leakage and corrosion. Common packaging materials showing chemical compatibility with room temperature PCMs include stainless steelpolypropylene and polyolefin.

Nanoparticles such as carbon nanotubes, graphite, graphene, metal and metal oxide can be dispersed in PCM. It is worth noting that inclusion of nanoparticles will not only alter thermal conductivity characteristic of PCM but also other characteristics as well, including latent heat capacity, sub-cooling, phase change temperature and its duration, density and viscosity. The new group of PCMs called NePCM.[123] NePCMs can be added to metal foams to build even higher thermal conductive combination.[124]

Thermal compositesEdit

Thermal composites is a term given to combinations of phase change materials (PCMs) and other (usually solid) structures. A simple example is a copper mesh immersed in paraffin wax. The copper mesh within paraffin wax can be considered a composite material, dubbed a thermal composite. Such hybrid materials are created to achieve specific overall or bulk properties.

Thermal conductivity is a common property targeted for maximization by creating thermal composites. In this case, the basic idea is to increase thermal conductivity by adding a highly conducting solid (such as the copper mesh or graphite[125]) into the relatively low-conducting PCM, thus increasing overall or bulk (thermal) conductivity.[126] If the PCM is required to flow, the solid must be porous, such as a mesh.

Solid composites such as fiberglass or kevlar prepreg for the aerospace industry usually refer to a fiber (the kevlar or the glass) and a matrix (the glue, which solidifies to hold fibers and provide compressive strength). A thermal composite is not so clearly defined but could similarly refer to a matrix (solid) and the PCM, which is of course usually liquid and/or solid depending on conditions. They are also meant to discover minor elements in the earth.

ApplicationsEdit

Phase-change material being employed in the treatment of neonates with birth asphyxia[127][128]
Anti-icing potential of solidified Phase Switching Liquid (S-PSL),[129] a class of phase change materials.

Applications[1][130] of phase change materials include, but are not limited to:

  • Thermal energy storage
  • Solar cooking
  • Cold Energy Battery
  • Conditioning of buildings, such as 'ice-storage'
  • Cooling of heat and electrical engines
  • Cooling: food, beverages, coffee, wine, milk products, green houses
  • Delaying ice and frost formation on surfaces[129]
  • Medical applications: transportation of blood, operating tables, hot-cold therapies, treatment of birth asphyxia[127]
  • Human body cooling under bulky clothing or costumes.
  • Waste heat recovery
  • Off-peak power utilization: Heating hot water and Cooling
  • Heat pump systems
  • Passive storage in bioclimatic building/architecture (HDPE, paraffin)
  • Smoothing exothermic temperature peaks in chemical reactions
  • Solar power plants
  • Spacecraft thermal systems
  • Thermal comfort in vehicles
  • Thermal protection of electronic devices
  • Thermal protection of food: transport, hotel trade, ice-cream, etc.
  • Textiles used in clothing
  • Computer cooling
  • Turbine Inlet Chilling with thermal energy storage
  • Telecom shelters in tropical regions. They protect the high-value equipment in the shelter by keeping the indoor air temperature below the maximum permissible by absorbing heat generated by power-hungry equipment such as a Base Station Subsystem. In case of a power failure to conventional cooling systems, PCMs minimize use of diesel generators, and this can translate into enormous savings across thousands of telecom sites in tropics.

Fire and safety issuesEdit

Some phase change materials are suspended in water, and are relatively nontoxic. Others are hydrocarbons or other flammable materials, or are toxic. As such, PCMs must be selected and applied very carefully, in accordance with fire and building codes and sound engineering practices. Because of the increased fire risk, flamespread, smoke, potential for explosion when held in containers, and liability, it may be wise not to use flammable PCMs within residential or other regularly occupied buildings. Phase change materials are also being used in thermal regulation of electronics.


This article uses material from the Wikipedia article
 Metasyntactic variable, which is released under the 
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